CH^+(1–0) and ^(13)CH^+(1–0) absorption lines in the direction of massive star-forming regions

We report the detection of the ground-state rotational transition of the methylidyne cation CH^+ and its isotopologue ^(13)CH^+ toward the remote massive star-forming regions W33A, W49N, and W51 with the HIFI instrument onboard the Herschel satellite. Both lines are seen only in absorption against the dust continuum emission of the star-forming regions. The CH^+ absorption is saturated over almost the entire velocity ranges sampled by the lines-of-sight that include gas associated with the star-forming regions (SFR) and Galactic foreground material. The CH^+ column densities are inferred from the optically thin components. A lower limit of the isotopic ratio [^(12)CH^+]/[^(13)CH^+] > 35.5 is derived from the absorptions of foreground material toward W49N. The column density ratio, N(CH^+)/N(HCO^+), is found to vary by at least a factor 10, between 4 and >40, in the Galactic foreground material. Line-of-sight ^(12)CH^+ average abundances relative to total hydrogen are estimated. Their average value, N(CH^+)/N_H > 2.6 × 10^(−8), is higher than that observed in the solar neighborhood and confirms the high abundances of CH^+ in the Galactic interstellar medium. We compare this result to the predictions of turbulent dissipation regions (TDR) models and find that these high abundances can be reproduced for the inner Galaxy conditions. It is remarkable that the range of predicted N(CH^+)/N(HCO^+) ratios, from 1 to ~50, is comparable to that observed

Nitrogen hydrides in interstellar gas: Herschel/HIFI observations towards G10.6-0.4 (W31C)

The HIFI instrument on board the Herschel Space Observatory has been used to observe interstellar nitrogen hydrides along the sight-line towards G10.6−0.4 in order to improve our understanding of the interstellar chemistry of nitrogen. We report observations of absorption in NH N = 1 ← 0, J = 2 ← 1 and ortho-NH_2 1_(1,1) ← 0_(0,0). We also observed ortho-NH_3 1_0 ← 0_0, and 2_0 ← 1_0, para-NH_3 2_1 ← 1_1, and searched unsuccessfully for NH^+. All detections show emission and absorption associated directly with the hot-core source itself as well as absorption by foreground material over a wide range of velocities. All spectra show similar, non-saturated, absorption features, which we attribute to diffuse molecular gas. Total column densities over the velocity range 11−54 km s^(−1) are estimated. The similar profiles suggest fairly uniform abundances relative to hydrogen, approximately 6 × 10^(−9), 3 × 10^(−9), and 3 × 10^(−9) for NH, NH_2, and NH_3, respectively. These abundances are discussed with reference to models of gas-phase and surface chemistry

Interstellar CH absorption in the diffuse interstellar medium along the sight-lines to G10.6–0.4 (W31C), W49N, and W51

We report the detection of the ground state N, J = 1, 3/2 → 1, 1/2 doublet of the methylidyne radical CH at ~532 GHz and ~536 GHz with the Herschel/HIFI instrument along the sight-line to the massive star-forming regions G10.6–0.4 (W31C), W49N, and W51. While the molecular cores associated with these massive star-forming regions show emission lines, clouds in the diffuse interstellar medium are detected in absorption against the strong submillimeter background. The combination of hyperfine structure with emission and absorption results in complex profiles, with overlap of the different hyperfine components. The opacities of most of the CH absorption features are linearly correlated with those of CCH, CN, and HCO^+ in the same velocity intervals. In specific narrow velocity intervals, the opacities of CN and HCO^+ deviate from the mean trends, giving rise to more opaque absorption features. We propose that CCH can be used as another tracer of the molecular gas in the absence of better tracers, with [CCH]/[H_2] ~3.2 ± 1.1 × 10^(−8). The observed [CN]/[CH], [CCH]/[CH] abundance ratios suggest that the bulk of the diffuse matter along the lines of sight has gas densities n_H = n(H) + 2n(H_2) ranging between 100 and 1000 cm^(−3)

Excitation and abundance of C_3 in star forming cores: Herschel/HIFI observations of the sight-lines to W31C and W49N

We present spectrally resolved observations of triatomic carbon (C_3) in several ro-vibrational transitions between the vibrational ground state and the low-energy ν_2 bending mode at frequencies between 1654−1897 GHz along the sight-lines to the submillimeter continuum sources W31C and W49N, using Herschel’s HIFI instrument. We detect C_3 in absorption arising from the warm envelope surrounding the hot core, as indicated by the velocity peak position and shape of the line profile. The sensitivity does not allow to detect C_3 absorption due to diffuse foreground clouds. From the column densities of the rotational levels in the vibrational ground state probed by the absorption we derive a rotation temperature (T_(rot)) of ~50−70 K, which is a good measure of the kinetic temperature of the absorbing gas, as radiative transitions within the vibrational ground state are forbidden. It is also in good agreement with the dust temperatures for W31C and W49N. Applying the partition function correction based on the derived T_(rot), we get column densities N(C_3) ~ 7−9 × 10^(14) cm^(−2) and abundance x(C_3) ~ 10^(−8) with respect to H_2. For W31C, using a radiative transfer model including far-infrared pumping by the dust continuum and a temperature gradient within the source along the line of sight we find that a model with x(C_3) = 10^(−8), T_(kin) = 30−50 K, N(C_3) = 1.5 × 10^(15) cm^(−2) fits the observations reasonably well and provides parameters in very good agreement with the simple excitation analysis

Discovery of Hydrogen Fluoride in the Cloverleaf Quasar at z = 2.56

We report the first detection of hydrogen fluoride (HF) toward a high redshift quasar. Using the Caltech Submillimeter Observatory (CSO) we detect the HF J = 1 - 0 transition in absorption toward the Cloverleaf, a broad absorption line (BAL) quasi-stellar object (QSO) at z=2.56. The detection is statistically significant at the ~ 6 sigma level. We estimate a lower limit of 4 \times 1014 cm-2 for the HF column density and using a previous estimate of the hydrogen column density, we obtain a lower limit of 1.7 \times 10-9 for the HF abundance. This value suggests that, assuming a Galactic N(HF)/NH ratio, HF accounts for at least ~10% of the fluorine in the gas phase along the line of sight to the Cloverleaf quasar. This observation corroborates the prediction that HF should be a good probe of the molecular gas at high redshift. Measurements of the HF abundance as a function of redshift are urgently needed to better constrain the fluorine nucleosynthesis mechanism(s)

Hydrogen Fluoride toward Luminous Nearby Galaxies: NGC 253 and NGC 4945

We present the detection of hydrogen fluoride, HF, in two luminous nearby galaxies NGC 253 and NGC 4945 using the Heterodyne Instrument for the Far-Infrared (HIFI) on board the Herschel Space Observatory. The HF line toward NGC 253 has a P-Cygni profile, while an asymmetric absorption profile is seen toward NGC 4945. The P-Cygni profile in NGC 253 suggests an outflow of molecular gas with a mass of M(H_2)_(out) ~ 1 × 10^7 M_⊙ and an outflow rate as large as Ṁ ~ 6.4 M_⊙ yr^(−1). In the case of NGC 4945, the axisymmetric velocity components in the HF line profile is compatible with the interpretation of a fast rotating nuclear ring surrounding the nucleus and the presence of inflowing gas. The gas falls into the nucleus with an inflow rate of ≤ 1.2 M_⊙ yr^(−1), inside a inner radius of ≤ 200 pc. The gas accretion rate to the central AGN is much smaller, suggesting that the inflow can be triggering a nuclear starburst. From these results, the HF J = 1 − 0 line is seen to provide an important probe of the kinematics of absorbing material along the sight-line to nearby galaxies with bright dust continuum and a promising new tracer of molecular gas in high redshift galaxies

Hydrogen chloride in diffuse interstellar clouds along the line of sight to W31C (G10.6-0.4)

We report the detection of hydrogen chloride, HCl, in diffuse molecular clouds on the line of sight toward the star-forming region W31C (G10.6-0.4). The J = 1-0 lines of the two stable HCl isotopologues, H^(35)Cl and H^(37)Cl, are observed using the 1b receiver of the Heterodyne Instrument for the Far-Infrared (HIFI) on board the Herschel Space Observatory. The HCl line is detected in absorption, over a wide range of velocities associated with diffuse clouds along the line of sight to W31C. The analysis of the absorption strength yields a total HCl column density of a few 10^(13) cm^(–2), implying that HCl accounts for ~0.6% of the total gas-phase chlorine, which exceeds the theoretical model predictions by a factor of ~6. This result is comparable to those obtained from the chemically related species H_2Cl^+ and HCl^+, for which large column densities have also been reported on the same line of sight. The source of discrepancy between models and observations is still unknown; however, the detection of these Cl-bearing molecules provides key constraints for the chlorine chemistry in the diffuse gas

Herschel observations of EXtraordinary Sources: Analysis of the full Herschel/HIFI molecular line survey of Sagittarius B2(N)

A sensitive broadband molecular line survey of the Sagittarius B2(N) star-forming region has been obtained with the HIFI instrument on the Herschel Space Observatory, offering the first high-spectral resolution look at this well-studied source in a wavelength region largely inaccessible from the ground (625-157 um). From the roughly 8,000 spectral features in the survey, a total of 72 isotopologues arising from 44 different molecules have been identified, ranging from light hydrides to complex organics, and arising from a variety of environments from cold and diffuse to hot and dense gas. We present an LTE model to the spectral signatures of each molecule, constraining the source sizes for hot core species with complementary SMA interferometric observations, and assuming that molecules with related functional group composition are cospatial. For each molecule, a single model is given to fit all of the emission and absorption features of that species across the entire 480-1910 GHz spectral range, accounting for multiple temperature and velocity components when needed to describe the spectrum. As with other HIFI surveys toward massive star forming regions, methanol is found to contribute more integrated line intensity to the spectrum than any other species. We discuss the molecular abundances derived for the hot core, where the local thermodynamic equilibrium approximation is generally found to describe the spectrum well, in comparison to abundances derived for the same molecules in the Orion KL region from a similar HIFI survey.Comment: Accepted to ApJ. 64 pages, 14 figures. Truncated abstrac